Product ID:POOL BREEZE
MSDS Date:01/20/1993
FSC:6850
NIIN:00N053992
MSDS Number: BVWCB

ICI AMERICAS INC

WILMINGTON, DE 19897
US

Emergency Phone: 800-327-8633

Info Phone: 302-886-3000

Cage: 1N759

ICI AMERICAS INC. (FILM DIVISION)

WILMINGTON, DE 19897 US

Telephone: 302-575-3000

Cage: 1N759

HYPOCHLOROUS ACID, CALCIUM SALT; (CALCIUM HYPOCHLORITE)

CAS: 7778-54-3

RTECS: NH3485000

Fraction By Weight: 65-75%

OSHA PEL 0.5 PPM (CHLORINE)

ACGIH TLV: 0.5 PPM (CHLORINE)

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

SODIUM CHLORIDE

CAS: 7647-14-5

RTECS: VZ4725000

Fraction By Weight: 10-20%

OSHA PEL N/K

ACGIH TLV: N/K

CHLORIC ACID, CALCIUM SALT; (CALCIUM CHLORATE)

CAS: 10137-74-3

RTECS: FN9800000

Fraction By Weight: 0-5%

OSHA PEL N/K

ACGIH TLV: N/K

CALCIUM CHLORIDE

CAS: 10043-52-4

RTECS: EV9800000

Fraction By Weight: 0-5%

OSHA PEL N/K

ACGIH TLV: N/K

NEOPRENE OR PVC.

CAS: 1305-62-0

RTECS: EW2800000

Fraction By Weight: 0-4%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 5 MG/M3

1); (CALCIUM CARBONATE)

CAS: 471-34-1

RTECS: FF9335000

OSHA PEL 15 MG/M3 (MFR)

ACGIH TLV: N/K

FOLLOWING INGEST OF THIS POTENTIALLY CORR MATL

RTECS: 9999999ZZ

INTOXICATION. SIMILARLY, GASTRIC LAVAGE IS NOT

RTECS: 9999999ZZ

HOUR OF INGESTION. IN CASES OF SEVERE ESOPHAGEAL

RTECS: 9999999ZZ

MONITORING OF GAS EXCHANGE, ACID-BASE BALANCE,

RTECS: 9999999ZZ

USE OF STEROIDS IS CONTROVERSIAL. IT HAS BEEN FOUND

RTECS: 9999999ZZ

BEEN IMPLICATED IN THE DEVELOPMENT OF PERITONEAL

RTECS: 9999999ZZ

PROD IS HAZ WASTE, NUMBER D001, UNDER

RTECS: 9999999ZZ

AND FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50: (ORAL, RAT) > 850 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INGEST: THIS MATERIAL IS CLASSIFIED AS
SLIGHTLY TOXIC. IRRITATION OR CHEMICAL BURNS OF MOUTH, PHARYNX,
ESOPHAGUS & STOMACH CAN DEVELOP FOLLOWING INGESTION. INJURY MAY BE
SEVERE & CAUSE DEATH. EYES: CA N INDUCE CHEMICAL BURNS ON CONTACT.
SKIN: WILL PROBABLY SEVERELY IRRITATE OR BURN SKIN. WILL PROBABLY
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: NOT BE ABSORBED THROUGH SKIN. INHAL:
DATA NOT AVAILABLE ON THIS MATERIAL. PARTICULATES OF THIS MATERIAL
WILL PROBABLY IRRITATE RESPIRATORY PASSAGES. PRODUCT HAS POTENTIAL
TO BE IMMEDIATELY D ANGEROUS TO LIFE/HEALTH. INHALATION OF HIGH
CONCENTRATIONS CAN RESULT IN PERMANENT LUNG DAMAGE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN: WASH MATL OFF SKIN W/SOAP & FLUSH W/PLENTY OF WATER FOR
AT LEAST 15 MIN. GET MED ATTN. WASH CONTAMD CLTHG & DECONTAM
FOOTWEAR BEFORE REUSE. EYES: IMMED FLUSH W/PLENTY OF WATER. AFTER
INITIAL FLU SHING, REMOVE ANY CNTCT LENSES & CONTINUE FLUSHING FOR
AT LEAST 15 MIN. HAVE EYES EXAMINED & TREATED BY MED PERS. INGEST:
GIVE 1 OR 2 GLASSES OF WATER TO DRINK & REFER TO MED PERS. (NEVER
(SUPDAT)

Extinguishing Media:USE WATER TO COOL CONTAINERS EXPOSED TO FIRE. DO
NOT USE DRY PWDR FIRE EXTINGUISHERS CONTAINING MONO-AMMONIUM
PHOSPHATE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:OXIDIZER MAY RELEASE CHLORINE, A
CORROSIVE AND FLAMMABLE GAS.

Spill Release Procedures:WEAR SKIN, EYE & RESPIRATORY PROTECTION DURING
CLEANUP. KEEP OUT OF SEWERS AND DRAINS. SWEEP UP AND RECOVER OR MIX
MATERIAL WITH A MOIST ABSORBENT AND SHOVEL INTO A CHEMICAL WASTE
CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP TIGHTLY SEALED. STORE IN COOL,
DRY, WELL VENTILATED AREA, AWAY FROM FLAMMABLE, COMBUSTIBLE OR
OTHER MATERIALS CAPABLE OF OXIDATION.
Other Precautions:FOLLOW PROCEDURES SPECIFIED IN THE NATIONAL
PROTECTION ASSOCIATION CODES & STANDARDS FOR HANDLING OXIDIZING
MATERIALS. PREVENT SKIN & EYE CONTACT. OBSERVE OSHA PEL
LIMITATIONS. AVOID BREATHING PARTICU LATES.

Respiratory Protection:IF NEEDED, USE NIOSH/MSHA APPROVED RESPIRATOR
WITH CHLORINE CARTRIDGES AND DUSTS/MISTS FILTER.
Ventilation:USE VENTILATION ADEQUATE TO MAINTAIN SAFE LEVELS.
Protective Gloves:NEOPRENE OR PVC GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 14)
Other Protective Equipment:EMER EYE WASH AND DELUGE SHOWER WHICH MEETS
ANSI DESIGN CRITERIA . USE BOOTS AND IMPERVIOUS APRON OF (ING 5)
Work Hygienic Practices:MINIMIZE EXPOSURE LIMITS IN ACCORDANCE WITH
GOOD HYGIENE PRACTICE.
Supplemental Safety and Health
PH: 10.5-11.5 @ 25C. MATL TO AVOID: CONTAINING CMPDS, CORR,
FLAMM/COMBUST MATLS. GLYCEROL, DIGLOMONOMETHYL ETHER OR PHENOL MAY
CAUSE IGNIT W/GENERATION OF IRRITANT SMOKE. FIRST AID PROC: GIVE
ANYTHING BY MOUTH TO UNCON PERSON). INHAL: REMOVE TO FRESH AIR.
CONSULT MED PERS IMMED. NOTE TO MD: MUCOSAL INJURY (ING 7)

HCC:D2
pH:SUPDAT
Solubility in Water:SOLUBLE 18% @ 25C
Appearance and Odor:WHITE FREE FLOWING POWDER; CHLORINE-LIKE ODOR.
Percent Volatiles by Volume:NEGLIG

Stability Indicator/Materials to Avoid:YES
CNTNR MUST BE CLEAN & FREE OF ORG RESIDUES. ACIDS, OTHER ORG SULFIDES,
OXIDIZERS, ALL CORR LIQS, NITROGEN (SUPDAT)
Stability Condition to Avoid:MAY DECOMPOSE IF EXPOSED TO HEAT OR DIRECT
SUNLIGHT.
Hazardous Decomposition Products:COMBUSTION PRODUCTS: HALOGEN, HALOGEN
ACIDS, POSSIBLE TRACE AMOUNTS OF CARBONYL HALIDE.

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FED, STATE & LOC REGS .
MATL IS TOX TO FISH. DO NOT CONTAM WATERWAYS BY CLEANING OF
EQUIP/BY DISP OF WASTES. UNTREATED EFFLUENT SHOULD NOT BE
DISCHARGED WHERE IT WILL DRAI N INTO LAKES, STREAMS OR PONDS.
DISCARDED (ING 13)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.